Direct extraction of alkylphenols, chlorophenols and bisphenol A from acid-digested sediment suspension for simultaneous gas chromatographic-mass spectrometric analysis SCIE SCOPUS

Cited 47 time in WEB OF SCIENCE Cited 0 time in Scopus
Title
Direct extraction of alkylphenols, chlorophenols and bisphenol A from acid-digested sediment suspension for simultaneous gas chromatographic-mass spectrometric analysis
Author(s)
Li, DH; Oh, JR; Park, J
Publication Year
2003-09-19
Abstract
The direct extraction of alkylphenols, chlorophenols and bisphenol A from an acid-digested sediment suspension for GC-MS analysis was studied. The sediment was digested with acid while the hydrolyzed analytes were being extracted with dichloromethane. The conditions of the acid digestion and extraction were optimized in terms of time, acidity of digestion, and extracting solvent. It is possible to complete the extraction within 20 min with 5 ml of 0.1 M HCl digesting solution and three portions of 5 ml of dichloromethane. The recoveries of analytes were mostly around 90% with about 10% relative standard deviations. With this technique parallel treatment of large numbers of sediment samples is possible without any expensive special equipment or heating process. The analytical characteristics of this extraction technique were compared with Soxhlet extraction and the pressurized liquid extraction technique. The technique was examined and evaluated for real environmental sediment samples and certified reference material of natural matrix. (C) 2003 Elsevier B.V. All rights reserved.
ISSN
0021-9673
URI
https://sciwatch.kiost.ac.kr/handle/2020.kiost/5449
DOI
10.1016/S0021-9673(03)01174-9
Bibliographic Citation
JOURNAL OF CHROMATOGRAPHY A, v.1012, no.2, pp.207 - 214, 2003
Publisher
ELSEVIER SCIENCE BV
Subject
ACCELERATED SOLVENT-EXTRACTION; PRIMARY DEGRADATION-PRODUCTS; TROUT ONCORHYNCHUS-MYKISS; LIQUID-CHROMATOGRAPHY; ETHOXYLATE SURFACTANTS; ENVIRONMENTAL-SAMPLES; NONYLPHENOL; FATE; 4-TERT-OCTYLPHENOL; PENTACHLOROPHENOL
Keywords
extraction methods; sediments; environmental analysis; alkylphenols; chlorophenols; bisphenol A; phenols
Type
Article
Language
English
Document Type
Article
Publisher
ELSEVIER SCIENCE BV
Files in This Item:
There are no files associated with this item.

qrcode

Items in ScienceWatch@KIOST are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse