PYE컬럼 HPLC와 GC-ECD를 이용한 연안환경 시료의 PBDEs의 분석

Title
PYE컬럼 HPLC와 GC-ECD를 이용한 연안환경 시료의 PBDEs의 분석
Alternative Title
PYE column HPLC and GC-ECD in the accurate determination of toxic polybrominated diphenyl ethers (PBDEs) in Korean coastal environments
Author(s)
Kannan; 홍상희; 임운혁; 이동호; 심원준; 오재룡
KIOST Author(s)
Hong, Sang Hee(홍상희)Yim, Un Hyuk(임운혁)Shim, Won Joon(심원준)
Publication Year
2005-03-22
Abstract
Measurement of toxicologically relevant Polychlorinated biphenyl (PCB) congeners such as non-ortho (IUPAC#) 77, 81, 126 and 169 and mono-ortho 105, 114, 118, 123, 156, 157, 189 and di-ortho 170, 180 and Polybrominated diphenyl ethers (PBDEs) such as 47, 66, 85, 99, 100, 138, 153, 154 in environmental samples become almost mandatory in several countries now. However, most of the available methods involve expensive instrumentations such as HRGC-HRMS or ECNI-LRMS, apart from expensive extraction and clean-up (large volume of solvents) steps. A method has been devised combining the analytical separation power of PYE [2-(1-pyrenyl)ethyldimethysilylated silica] column HPLC and high-resolution gas chromatographic techniques including micro- electron capture detection (ECD) and two dimensional gas chromatograpy-ECD techniques to determine these eco-toxic substances at parts-per-trillion (ppt) levels. This combination resolves co-elution of congeners that occur in disproportationate ratios (eg. CB-110 and -77) and allows accurate congener-specific determination of target compounds. This method is cost effective as it involves only hexane, that in small quanties (10ml) and GC-ECD. The elution and analysis time are optimized to involve less human hours. This method is effectively utilized in the analysis of co-planar CBs and PBDEs from archived solvent extracts of samples previously analysed for pesticides and PCBs. Structure based separation of contaminant classes improves GC-ECD determination with extreme low volume micro-concentration at ppt levels.
URI
https://sciwatch.kiost.ac.kr/handle/2020.kiost/31572
Bibliographic Citation
2005 수산과학원-해양연구원 해양환경분야 공동세미나, pp.105 - 122, 2005
Publisher
수산과학원
Type
Conference
Language
English
Publisher
수산과학원
Related Researcher
Research Interests

Microplastic pollution,Persistent Organic Pollutants,Oil Pollution,미세플라스틱 오염,잔류성 유기오염물질,유류오염

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