Mild Isomerative Opening of Tetrahydrofuranyl Subunits in Steroids Using TFAT (trifluoroacetyl trifluoromethanesulfonate): Application to Synthesis of C17-OH Rockogenin Acetate SCIE SCOPUS KCI
DC Field | Value | Language |
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dc.contributor.author | Lee, Jong Seok | - |
dc.contributor.author | Kim, Byungsook | - |
dc.contributor.author | Shin, Junho | - |
dc.contributor.author | Lee, Yeon-Ju | - |
dc.contributor.author | Shin, Hee Jae | - |
dc.contributor.author | Lee, Hyi-Seung | - |
dc.date.accessioned | 2020-04-20T06:55:42Z | - |
dc.date.available | 2020-04-20T06:55:42Z | - |
dc.date.created | 2020-02-04 | - |
dc.date.issued | 2012-01-20 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | https://sciwatch.kiost.ac.kr/handle/2020.kiost/3642 | - |
dc.description.abstract | A novel and efficient tetrahydrofuranyl ring opening method was developed using the highly reactive TFAT reagent in the presence of an acid scavenger, 2,6-di-tert-butyl-4-methylpyridine. Various acid sensitive groups are compatible with the reaction condition, making it generally applicable to many tetrahydrofuranyl steroids. Moreover, it is a synthetic equivalent of 'Marker degradation' affording an efficient synthesis of C17-OH rockogenin acetate. | - |
dc.description.uri | 1 | - |
dc.language | English | - |
dc.publisher | KOREAN CHEMICAL SOC | - |
dc.subject | SULFENE ELIMINATION LEADS | - |
dc.subject | SIDE-CHAIN | - |
dc.subject | 2-OXA-CIS-DECALIN SKELETON | - |
dc.subject | ENANTIOSELECTIVE SYNTHESIS | - |
dc.subject | CEPHALOSTATIN SYNTHESIS | - |
dc.subject | RITTERAZINE-M | - |
dc.subject | SAPOGENINS | - |
dc.subject | CONVENIENT | - |
dc.subject | HEMISPHERE | - |
dc.subject | OXIDATION | - |
dc.title | Mild Isomerative Opening of Tetrahydrofuranyl Subunits in Steroids Using TFAT (trifluoroacetyl trifluoromethanesulfonate): Application to Synthesis of C17-OH Rockogenin Acetate | - |
dc.type | Article | - |
dc.citation.endPage | 82 | - |
dc.citation.startPage | 76 | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 33 | - |
dc.citation.number | 1 | - |
dc.contributor.alternativeName | 이종석 | - |
dc.contributor.alternativeName | 김병숙 | - |
dc.contributor.alternativeName | 신준호 | - |
dc.contributor.alternativeName | 이연주 | - |
dc.contributor.alternativeName | 신희재 | - |
dc.contributor.alternativeName | 이희승 | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.33, no.1, pp.76 - 82 | - |
dc.identifier.doi | 10.5012/bkcs.2012.33.1.76 | - |
dc.identifier.scopusid | 2-s2.0-84862950180 | - |
dc.identifier.wosid | 000300473700013 | - |
dc.type.docType | Article | - |
dc.identifier.kciid | ART001628774 | - |
dc.description.journalClass | 1 | - |
dc.subject.keywordPlus | SULFENE ELIMINATION LEADS | - |
dc.subject.keywordPlus | SIDE-CHAIN | - |
dc.subject.keywordPlus | 2-OXA-CIS-DECALIN SKELETON | - |
dc.subject.keywordPlus | ENANTIOSELECTIVE SYNTHESIS | - |
dc.subject.keywordPlus | CEPHALOSTATIN SYNTHESIS | - |
dc.subject.keywordPlus | RITTERAZINE-M | - |
dc.subject.keywordPlus | SAPOGENINS | - |
dc.subject.keywordPlus | CONVENIENT | - |
dc.subject.keywordPlus | HEMISPHERE | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordAuthor | Steroid | - |
dc.subject.keywordAuthor | TFAT (trifluoroacetyl trifluoromethanesulfonate) | - |
dc.subject.keywordAuthor | Ring opening | - |
dc.subject.keywordAuthor | Dihydroxylation | - |
dc.subject.keywordAuthor | Alkoxyl radical cyclization | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.relation.journalResearchArea | Chemistry | - |